[China Glass Net] By analyzing the surface composition of the coated glass on the surface of the glass by magnetron sputtering, the cause of the mold was explored. Scanning electron microscopy-energy spectrometer and X-ray photoelectron spectroscopy were used to analyze the moldy and unmold areas of the coated glass, and compared with the ground samples, the main reasons for the mildew of the coated glass were discussed. The in-depth analysis of the coated glass for marine transportation is carried out to detect changes in the distribution of elements along the depth. Star-shaped white spots appeared on the surface of the coated glass. The surface of the coated glass was fluorine-containing by XPS test. The fluorine content was 0.12% and the diffusion depth was about 11 nm. The fluorine content in the white spot was 1.07%, and the diffusion depth was about 65 nm. And the Na element has diffused slightly to the surface of the sample. During the marine transportation process, the coated glass is in contact with the fluorine-containing substances from the ocean for a long time, the SiO2 which protects the top layer of the film is eroded, and the SiO2 film layer is peeled off, causing a large amount of water vapor to contact the coated glass, and the soluble silicate in the surface layer. It is hydrolyzed and destroyed to form caustic soda, which causes a large area of ​​mold on the glass.

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